Tetraethylammonium [1-methylimidazole-2(3H)-thione]copper(I)-di-μ-sulfido-dioxotungstate(VI)
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چکیده
منابع مشابه
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
Hexamethyl-phospho-ramide (hmp), tetra-thio-molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n-) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti-prismatic environment. To...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
In the title salt, {[Ho(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the anion forms a W/S/Ag polymeric chain along the a axis. The holmium atom in the cation is coordinated by eight O atoms from two nitrate and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the complex cation in the title compound is univalent, whic...
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In the title compound, (C(6)H(17)N(3))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion is formed by two edge-sharing GeS(4) tetra-hedral units. The average terminal and bridging Ge-S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N-H⋯S hydrogen bonds.
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)terbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
In the title compound, {[Tb(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the polymeric anionic chain {[AgWS(4)](-)}(n) extends along [001]. The Tb(III) atom in the cation is coordinated by eight O atoms from two nitrate and four hexamethylphosphate ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is univalent, which leads to the anionic ch...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)erbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
In the title compound, {[Er(NO3)2(C6H18N3OP)4][AgWS4]} n , the polymeric anionic chain {[AgWS4](-)} n extends along [001]. The Er(III) atom in the cation is coordinated by eight O atoms from two bidentate nitrate anions and four hexa-methyl-phospho-ramide ligands in a distorted square-anti-prismatic geometry. Together with the two nitrate ligands, the cation is monovalent, which leads to the an...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2004
ISSN: 1600-5368
DOI: 10.1107/s1600536804030132